• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to an anhydrous cosmetic composition based on bicarbonate salt, as well as its cosmetic use as a deodorant. It also relates to a deodorant product containing this composition.
    公开号:FR3036285A1
    申请号:FR1554552
    申请日:2015-05-21
    公开日:2016-11-25
    发明作者:Magali Millet；Florian Salles
    申请人:Laboratoires M&L SA；
    IPC主号:
    专利说明:

    [0001] FIELD OF THE INVENTION The present invention relates to an anhydrous cosmetic composition based on bicarbonate salt, as well as its cosmetic use as a deodorant. It also relates to a deodorant product containing this composition. BACKGROUND OF THE INVENTION Deodorants and antiperspirants have become hygiene products as essential as shampoos and toothpastes. If the former act on perspiration odors either by camouflaging them, or by targeting the bacteria feeding on apocrine sweat, or by absorbing perspiration, the latter regulate the amount of sweat emitted. The safety of aluminum salts used as antiperspirants has been questioned in recent years, leading consumers to consider products containing natural deodorant agents such as talc and / or certain plants. dried form or in the form of essential oils. The effectiveness of these products is not always optimal.
    [0002] Sodium bicarbonate is a recognized natural deodorant active. At the doses considered effective, its formulation is, on the other hand, complicated by its incompatibility with many raw materials, in particular when it has to be formulated in anhydrous solid or semi-solid compositions having good cosmetic properties. SUMMARY OF THE INVENTION After much research, we have developed a composition in which effective amounts of bicarbonate salt can be associated with a significant amount of oils without adversely affecting the stability of the composition. It is thus possible to formulate anhydrous deodorants in the form of cream or sticks of flexible texture, based on ingredients of natural origin. These compositions have been found to be easy to apply, effective against perspiration odors and capable of depositing on the skin a soft, non-greasy and non-sticky film. The subject of the invention is thus an anhydrous cosmetic composition comprising: (a) from 1 to 20% by weight of at least one bicarbonate salt, (b) from 20 to 50% by weight of at least one oil, (c) at least one fatty phase structurant, (d) glycerin, and (e) at least one polyglycerol ester and a fatty acid containing from 12 to 30 carbon atoms. It also relates to the cosmetic use of this composition for treating human body odor, especially axillary odors.
    [0003] Finally, it relates to a deodorant product in the form of a tube, pot or any other packaging, in particular of oblong shape, suitable for dispensing a semi-solid composition, containing the composition according to the invention in the form of cream, or in the form of conditioning adapted to distribute a stick, containing the composition according to the invention in stick form.
    [0004] DETAILED DESCRIPTION The composition according to the invention is an anhydrous composition, in that it contains less than 5% by weight of water, advantageously less than 1% by weight of water, which can be provided solely by its constituent ingredients. It is preferred that it does not contain water. It comprises a salt of bicarbonate as a deodorant agent. This may represent from 1 to 20% by weight, and preferably from 5 to 15% by weight, relative to the total weight of the composition. As bicarbonate salts, there may be mentioned sodium, potassium, magnesium and ammonium salts, the sodium salt being preferred for use in this invention. According to one embodiment, the composition does not contain aluminum salts. On the other hand, it may however contain at least one additional deodorant active agent chosen from: bacteriostatic or bactericidal agents, such as chlorhexidine and its salts; triclosan; triclocarban; farnesol; essential oils of vegetable origin, chosen for example from the essential oils of oregano, palmarosa, peppermint, lavender, lemon and tea tree; plant extracts such as grapefruit seed extracts; zinc salts such as gluconate, pidolate and zinc ricinoleate; and their mixtures. As indicated above, it has been observed that the composition according to the invention is stable in the presence of bicarbonate, even though it contains large amounts of oil, namely from 20 to 50% by weight, and especially from 25 to 40% by weight, of one or more oils, relative to the total weight of the composition. For the purposes of the present invention, the term "oil" means a compound which is liquid at ambient temperature (25 ° C.) and atmospheric pressure (105 Pa) which, when introduced at a rate of at least 1% by weight in the water at 25 ° C is not at all soluble in water, or soluble to less than 10% by weight, based on the weight of oil introduced into the water. The oils can be volatile or nonvolatile. By "non-volatile oil" is meant in this specification an oil remaining on the skin at 25 ° C and atmospheric pressure for at least one hour, in the absence of friction, and / or having a vapor pressure of less than 0.001. mm Hg under these conditions. The oils included in the composition according to the invention may or may not be volatile; they are advantageously non-volatile. Alternatively, it may be a mixture of non-volatile (predominant by weight) and volatile (minority by weight) oils. Examples of volatile oils include linear C11 to C14 alkanes. In addition, it is preferred that the nonvolatile oils be selected from hydrocarbon oils, i.e. they exclusively contain carbon, hydrogen and optionally oxygen atoms. Examples of non-volatile oils include: - acid and mono-alcohol esters selected from: mono- and polyesters of C2-C10 (preferably C6-C10) saturated linear acids and mono- and polyesters; saturated C10-C18 linear alcohols (preferably C10-C14), mono- and polyesters of C10-C20 saturated linear acids and C3-C20 branched or unsaturated mono-alcohols (preferably C3-C10) ; mono- and polyesters of branched or unsaturated C 5 -C 20 acids and C 5 -C 20 branched or unsaturated mono-alcohols; mono- and polyesters of branched or unsaturated C 5 -C 20 acids and C 2 -C 4 linear monoalcohols; triglycerides of C6-C12 fatty acids, such as triglycerides of caprylic and capric acids and triheptanoin; branched and / or unsaturated C10-C20 fatty acids (such as linoleic, lauric and myristic acids); branched and / or unsaturated C10-C20 fatty alcohols (such as octyldodecanol and oleyl alcohol); Hydrocarbons such as vegetable squalane extracted from olive oil; dialkyl carbonates, such as dicaprylyl carbonate and diethylhexyl carbonate; dialkyl ethers such as dicaprylyl ether; and - their mixtures.
    [0005] There may also be mentioned vegetable oils which contain one or more of the aforementioned constituents. As esters of acids and monoalcohols which constitute the preferred class of nonvolatile oils according to the invention, mention may be made especially of monoesters such as the mixture of coconut caprate and caprylate, ethyl macadamate and the ester. shea butter ethyl ester, isostearyl isostearate, isononyl isononanoate, ethylhexyl isononanoate, hexyl neopentanoate, ethylhexyl neopentanoate, isodecyl neopentanoate, isostearyl neopentanoate , isodecyl neopentanoate, isopropyl myristate, octyldodecyl myristate, isopropyl palmitate, ethylhexyl palmitate, hexyl laurate, isoamyl laurate, cetostearyl nonanoate, propylheptyl capylate and mixtures thereof. Other useful esters are diesters of acids and monohydric alcohols such as disopropyl adipate, diethylhexyl adipate, diisopropyl sebacate and diisoamyl sebacate.
    [0006] Examples of vegetable oils include wheat germ, sunflower, argan, hibiscus, coriander, grape seed, sesame, corn, apricot, castor oil and shea oils. avocado, olive, soya, sweet almond oil, 3036285 5 palm, rapeseed, cotton, hazelnut, macadamia, jojoba, alfalfa, poppy, pumpkin, sesame, squash, rapeseed, blackcurrant, evening primrose, lavender, borage, millet, barley, quinoa, rye, safflower, bancoulier, passionflower, rose hip or camellia. In order to obtain a stable composition having good cosmetic properties, the composition according to the invention also contains a combination of at least one fatty phase structurant with glycerin and at least one polyglycerol and fatty alcohol ester containing 12 at 30 carbon atoms. The term "fatty phase structurant" is intended to mean a compound capable of thickening the oils contained in the composition, chosen in particular from waxes, fatty phase gelling agents and pasty fatty substances, as well as mixtures thereof.
    [0007] The term "wax" refers, in the context of this specification, to a solid body at 25 ° C., having a reversible solid / liquid state change, having a melting point of generally between 30 and 160 ° C., preferably between 50 and 90 ° C, as measured by DSC. Examples of waxes are, in particular, waxes of animal or vegetable origin, such as beeswax, Chinese insect wax, candelilla wax, carnauba wax or acacia wax; hydrogenated vegetable oils optionally modified with isostearic acid, especially hydrogenated rapeseed, soybean, sunflower, jojoba, coconut and castor oil; saturated C14-C30 linear fatty acid esters and C16-C36 saturated linear fatty alcohols; linear and saturated C10-C30 acids; linear and saturated C8-C30 alcohols; and their mixtures. These waxes may be in micronized form, that is to say in the form of a powder whose particles have a number average size of less than or equal to 50 μm, and in particular ranging from 0.5 to 50 μm. preferably from 1 to 30 μm, or even from 3 to 20 μm, where the "average number size" corresponds to the size given by the statistical half-size distribution, called D50.
    [0008] By "fat phase gelling agents", reference is made to compounds that modify the rheology of the fatty phase by forming a three-dimensional network. Such compounds include, in particular, clays (in particular hydrophobic modified bentonites and hectorites), especially with di-stearyl dimethyl ammonium chloride; hydrophobic modified pyrogenic silicas; palmitate and dextrin myristate; polyamides, olefin (s) / styrene copolymers, poly (alkyl acrylates); glycerides of C16-C26 fatty acids (preferably linear and saturated) such as the compound Nomcort® HKG; cellulose derivatives and mixtures containing them; and their mixtures. Some hydrogenated vegetable oils can also be considered as fat phase gelling agents. Finally, the pasty fatty substances that can be used as fatty phase structuring agents are defined as reversible liquid / solid state change fatty substances, having in the solid state an anisotropic crystalline organization and comprising at a temperature of 23.degree. liquid and a solid fraction. It is preferred to use vegetable butters. Shea butters, cocoa and mango are examples of such pasty fats.
    [0009] According to a preferred embodiment, the fatty phase structurant included in the composition according to the invention consists of at least one ingredient chosen from animal waxes, waxes of vegetable origin and phase gelling agents. fat and mixtures thereof, optionally combined with at least one vegetable butter. More preferably still, the fatty phase structurant consists of a combination of at least one animal and / or vegetable wax with at least one fatty phase gelling agent. These fatty phase structuring agents can represent from 5 to 40%, and preferably from 15 to 30% of the total weight of the composition.
    [0010] Another constituent of the composition according to the invention, contributing to its stability, is glycerine. This may represent from 1 to 15% and preferably from 3 to 10% by weight of the composition.
    [0011] The composition according to the invention also contains at least one polyglycerol ester and a fatty acid containing from 12 to 30 and preferably from 18 to 22 carbon atoms. The fatty acid may be chosen from saturated linear acids, saturated branched acids, monounsaturated linear acids and mixtures thereof. These acids may optionally be mono- or polyhydroxylated. Examples of such compounds include stearic acid, isostearic acid, capric acid, arachidic acid, behenic acid, hydroxypalmitic acid, hydroxystearic acid, oleic acid and erucic acid. The polyglycerol can be obtained by condensation of two to six glycerol units. It is preferably polyglycerol-3 or -4. The polyglycerol may be partially or fully esterified to obtain the ester used in the present invention. It may especially be the product of the esterification of a wax using polyglycerol. A product of this type is commercially available from Gattefosse under the trade name Acticire®.
    [0012] This ester may represent from 0.1 to 5% and preferably from 0.5 to 3% of the total weight of the composition. The composition according to the invention preferably further comprises one or more pulverulent fillers, which are adapted to absorb moisture and sweat and which are generally in the form of porous or hollow microparticles, preferably porous. These microparticles are in principle substantially spherical. These fillers may especially be chosen from: organic fillers such as: polysaccharide powders and in particular native starch, modified starch and cellulose; acrylic polymer powders such as poly (methyl methacrylate), polyamides or polyolefins; dried algae powders such as Corallina officinalis; inorganic fillers such as silica, clays, perlite and talc; - and their mixtures.
    [0013] The starches are preferably selected from corn starch, rice starch, tapioca starch or wheat starch. Modified starches are preferred organic fillers for use in this invention. Examples of modified starches are optionally pre-gelatinized and / or oxidized starches, which are esterified with alkenylsuccinic anhydride, in particular with octenylsuccinic or dodecylsuccinic anhydride, optionally in the presence of calcium chloride, as well as the etherified starches, especially hydroxypropylated or carboxymethylated, and cationic starches, especially quaternized. Mention may also be made of starch crosslinked with sodium trimetaphosphate. As inorganic filler, it is preferred to use silica. These fillers can represent from 10 to 30% by weight, and preferably from 15 to 30% by weight, relative to the total weight of the composition. It may furthermore comprise additives chosen in particular from perfumes, antioxidants such as tocopherol, dyes, preservatives and their mixtures.
    [0014] It is preferred that the composition according to the invention contains an amount of at least 90% by weight of ingredients of plant origin, as determined according to ASTM D7026.
    [0015] The composition described above may be used as a deodorant product, which may be in the form of a cream (preferably having the texture of a balm) or a stick advantageously having a supple texture. EXAMPLES The invention will be better understood in light of the following examples, which are given for illustrative purposes only and are not intended to limit the scope of the invention as defined by the appended claims.
    [0016] Example 1: Deodorant Balm A balm was prepared by mixing the ingredients, and in the weight proportions, shown below.
    [0017] 30 Vegetable butters 20.00% Vegetable waxes and ester * 9.00% Vegetable oils 24.00% Glycerin 6.00% 3036285 9 Sodium bicarbonate 10.00% Modified starch 23.00% Silica 2.00% Essential oils qs 5 Antioxidant qs Perfume qs Total: 100,00% * of which AGTIEFOSSE Acticire, containing esters of C12-C30 fatty acids of polyglycerol-3.
    [0018] This balm can be packaged in pots and removed using a spatula. Example 2: Deodorant Balm 15 Vegetable Butters 20.00% Vegetable Waxes and Ester * 9.00% Vegetable Oils 33.00% Glycerin 6.00% Sodium Bicarbonate 10.00% 20 Native Starches 20.00% Antioxidant 0 , 20% Fragrance 1.50% * of which actieire of GATIEFOSSE, containing esters of C12-C30 fatty acids of polyglycerol-3.
    [0019] Example 3: Stability test Four samples A to D of the composition of Example 1 were taken and distributed into four pillboxes stored at 4 ° C, 25 ° C, 40 ° C and 50 ° C, respectively. The stability of samples A to C is evaluated weekly for 1 month then every 15 days for 2 months and that of sample D is evaluated weekly for 1 month.
    [0020] For comparative purposes, the stability of a similar product was evaluated, including: vegetable butter, vegetable oils, glycerine, sodium bicarbonate, starch, essential oils and antioxidant. This product did not contain any polyglycerol ester, wax, or fat phase gelling agent. It was also divided into four samples, as previously described. The appearance of the tested samples was observed. The results are shown in the table below: Tested product After 3 months at 4 ° C. After 3 months at 25 ° C. After 3 months at 40 ° C. After 1 month at 50 ° C. Example 1 stable stable stable stable Comparison stable stable phase shift aspect as soon as granular; 1 week and exudation from browning 1 week and darker color It follows from this test that the product according to the invention is more stable at 40 ° C, that is to say in accelerated aging conditions which are considered representative the behavior of the stored product for three years under normal storage conditions. Example 4: Sensory Analysis A panel of 19 volunteers was recruited to evaluate the balm of Example 1. The product was applied under the armpits with a spatula, followed by a massage to penetrate the skin. The panelists mainly considered that the product was easy to apply (17/19), limited the formation of perspiration odors (17/19) and provided good deodorant protection (16/19), without leaving any trace on the clothing (15/19).
    [0021] Example 5: Sensory Analysis - Comparative Test The balm of Example 2 was compared to a similar product, containing: vegetable butter, vegetable oils, glycerin, sodium bicarbonate, starch Essential oils and an antioxidant. This product did not contain any polyglycerol ester, wax, or fat-phase gelling agent. To do this, 9 volunteers were recruited. On the morning of the test, they were asked to wash their underarms with a neutral soap before applying, using a spatula, 0.4 to 0.5g of the balm of Example 2 under a armpit and the same amount of comparative balm 10 under the other armpit. The panelists then donned a black Lycra t-shirt, washed beforehand with a neutral detergent, which they kept all day. The effectiveness of the balms was self-assessed after 8 hours at the test laboratory.
    [0022] The balm of Example 2 was more effective than the comparative balm against perspiration odors after 8h (no odor for 8 panelists versus 6 panelists). It also generated less marks on the T-shirt (no trace for 5 panelists against 3 panelists). In addition, panelists preferred the softer texture of the balm of Example 2.
    权利要求:
    Claims (9)
    [0001]
    REVENDICATIONS1. Anhydrous cosmetic composition comprising: (a) from 1 to 20% by weight of at least one bicarbonate salt, (b) from 20 to 50% by weight of at least one oil, (c) at least one phase structurant fat, (d) glycerine, and (e) at least one polyglycerol ester and a fatty acid containing from 12 to 30 carbon atoms. 10
    [0002]
    2. Composition according to Claim 1, characterized in that the bicarbonate salt represents from 5 to 15% by weight, relative to the total weight of the composition.
    [0003]
    3. Composition according to any one of claims 1 or 2, characterized in that the fatty phase structurant consists of at least one ingredient selected from animal waxes, waxes of vegetable origin, gelling agents. fatty phase and mixtures thereof, optionally combined with at least one vegetable butter, more preferably the fatty phase structurant consists of a combination of at least one animal wax and / or vegetable with at least one fatty phase gelling agent. 20
    [0004]
    4. Composition according to any one of revendicatiosn 1 to 3, characterized in that the glycerin is 1 to 15% by weight, preferably 3 to 10% by weight, relative to the total weight of the composition. 25
    [0005]
    5. Composition according to any one of claims 1 to 4, characterized in that it further contains one or more pulverulent fillers in the form of porous or hollow microparticles, preferably chosen from modified starches, silica and mixtures thereof. 30
    [0006]
    6. Composition according to any one of claims 1 to 5, characterized in that the pulverulent fillers represent from 10 to 30% by weight, and preferably from 15 to 30% by weight, relative to the total weight of the composition. 3036285 13
    [0007]
    7. Cosmetic use of the composition according to any one of claims 1 to 6 for treating human body odors, in particular axillary odors.
    [0008]
    8. Deodorant product in the form of a tube, pot or any other packaging, in particular of oblong shape, suitable for dispensing a semi-solid composition, containing the composition according to any one of Claims 1 to 6 in cream form.
    [0009]
    9. Deodorant product in the form of conditioning adapted to distribute a stick, containing the composition according to any one of claims 1 to 6 in the form of a stick.
    类似技术:
    公开号 | 公开日 | 专利标题
    EP3297732B1|2019-03-06|Anhydrous deodorant composition made from bicarbonate
    FR2721210A1|1995-12-22|Cleaning composition containing lipid grains.
    EP3160425B1|2020-10-14|Anhydrous composition comprising a lipophilic gelling agent, at least two distinct fillers and a fatty phase
    EP3468523A1|2019-04-17|Hydrating lip balm composition
    FR2966360A1|2012-04-27|Cosmetic composition, useful for the cosmetic treatment of keratin materials, e.g. skin, eyes and scalp, comprises a mixture of at least two behenic acid ester and glycerol and at least one glycerol ester and fatty acid
    EP3468529A1|2019-04-17|Sunblock formulation comprising high linoleic acid natural oils and method of preparing
    EP3016633A2|2016-05-11|Cosmetic composition comprising a pasty fatty substance and a non-ionic derivative of cellulose which is hydrophobically modified
    EP3124011A1|2017-02-01|Concentrated cosmetic formulation base
    EP3630050B1|2021-02-24|Bicarbonate-based aqueous cosmetic composition
    FR2967060A1|2012-05-11|POWDER COMPOSITION COMPRISING AT LEAST ONE ESSENTIAL OIL, MODIFIED TAPIOCA STARCH
    FR3022771A1|2016-01-01|COSMETIC COMPOSITION COMPRISING SILICONE SILICA AND OILS
    WO2018211211A1|2018-11-22|Biphasic cosmetic composition
    FR3062059A1|2018-07-27|BASE OF CONCENTRATED COSMETIC FORMULATION DESCRIPTION
    FR3066914B1|2019-07-12|FISHED COSMETIC COMPOSITION WITH HIGH VEGETABLE BUTTER CONTENT
    FR3088197A1|2020-05-15|COSMETIC COMPOSITION CAPABLE OF CONVERTING TO POWDER
    FR3049191B1|2019-06-28|COSMETIC COMPOSITION IN THE FORM OF EMULSION SUITABLE FOR TRANSFORMING INTO OIL
    FR3112952A1|2022-02-04|Cosmetic composition comprising kpangnan butter and hydroxyapatite
    FR2988587A1|2013-10-04|SELF-EMULSIFYING COMPOSITION
    FR3067931A1|2018-12-28|COSMETIC POWDER COMPOSITION BASED ON OIL-IN-WATER DISPERSION COATED WITH SILICA HYDROPHOBIC AEROGEL PARTICLES
    EP3833447A1|2021-06-16|Anhydrous cosmetic composition comprising vegetable oil
    JP2018100265A|2018-06-28|Oily composition
    FR2955490A1|2011-07-29|COSMETIC AND / OR DERMATOLOGICAL COMPOSITION IN THE FORM OF GEL FOR TOPICAL APPLICATION
    同族专利:
    公开号 | 公开日
    ES2729073T3|2019-10-30|
    US10376450B2|2019-08-13|
    US20180168954A1|2018-06-21|
    FR3036285B1|2017-06-02|
    WO2016185113A1|2016-11-24|
    EP3297732A1|2018-03-28|
    EP3297732B1|2019-03-06|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US5376363A|1991-05-03|1994-12-27|Bristol-Myers Squibb Company|Clear gelled antiperspirant stick composition|
    CA2808807A1|2013-03-07|2014-09-07|Knowlton Development Corporation Inc.|Deodorant with improved endurance and stability|FR3072029A1|2017-10-09|2019-04-12|L'oreal|METHOD FOR TREATING HUMAN TRANSPIRATION USING A CATION AND ANION IN THE PRESENCE OF A MODULATOR|US4382079A|1977-10-25|1983-05-03|Colgate/Palmolive|Bicarbonate containing stick deodorant|
    US4832945A|1986-05-28|1989-05-23|Osipow Lloyd I|Deodorant stick|
    US5254332A|1992-03-20|1993-10-19|Church & Dwight Co., Inc.|Low residue antiperspirant sticks|
    US5482702A|1993-04-27|1996-01-09|Church & Dwight Co., Inc.|Hydrophilic polymer-coated microcrystallites of bicarbonate salt|
    US5628990A|1995-10-25|1997-05-13|Church & Dwight Co., Inc.|Anhydrous cosmetic product containing deodorant and desiccant ingredients|
    US6719965B2|2002-02-19|2004-04-13|Unilever Home & Personal Care Usa Division Of Conopco, Inc.|Antiperspirant or deodorant composition|
    US6726901B2|2002-05-09|2004-04-27|The Gillette Company|Stabilized antiperspirant compositions containing aluminum-zirconium salts with low M:Cl ratio|
    US7892525B2|2003-08-22|2011-02-22|Lubrizol Advanced Materials, Inc.|Antiperspirant gel compositions|
    EP2105125A1|2008-03-26|2009-09-30|Bayer MaterialScience AG|Skin care composition|
    FR2978036B1|2011-07-22|2013-07-19|Oreal|PROCESS FOR TREATING TRANSPIRATION USING AN ANHYDROUS COMPOSITION COMPRISING TWO REAGENTS PRODUCING IN-SITU ASSEMBLY ON THE SKIN A TRANSPIRING EFFECT|DE102016221154A1|2016-10-27|2018-05-03|Henkel Ag & Co. Kgaa|Cosmetic compositions containing a combination of at least two different active ingredients|
    FR3066915B1|2017-06-02|2019-07-26|Laboratoires M&L|AQUEOUS COSMETIC COMPOSITION BASED ON BICARBONATE|
    DE102018220966A1|2018-12-04|2020-06-04|Henkel Ag & Co. Kgaa|DEODORANT COMPOSITIONS INCLUDING CALCIUM SILICATE AND SODIUM BICARBONATE|
    DE102018222056A1|2018-12-18|2020-06-18|Henkel Ag & Co. Kgaa|Anhydrous deodorant aerosol containing sodium hydrogen carbonate|
    法律状态:
    2016-05-17| PLFP| Fee payment|Year of fee payment: 2 |
    2016-11-25| PLSC| Search report ready|Effective date: 20161125 |
    2017-05-16| PLFP| Fee payment|Year of fee payment: 3 |
    2018-05-21| PLFP| Fee payment|Year of fee payment: 4 |
    2019-05-20| PLFP| Fee payment|Year of fee payment: 5 |
    2020-05-12| PLFP| Fee payment|Year of fee payment: 6 |
    2021-05-21| PLFP| Fee payment|Year of fee payment: 7 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1554552A|FR3036285B1|2015-05-21|2015-05-21|ANHYDROUS DEODORANT COMPOSITION BASED ON BICARBONATE|FR1554552A| FR3036285B1|2015-05-21|2015-05-21|ANHYDROUS DEODORANT COMPOSITION BASED ON BICARBONATE|
    US15/575,590| US10376450B2|2015-05-21|2016-05-10|Anhydrous deodorant composition made from bicarbonate|
    EP16726362.3A| EP3297732B1|2015-05-21|2016-05-10|Anhydrous deodorant composition made from bicarbonate|
    ES16726362T| ES2729073T3|2015-05-21|2016-05-10|Bicarbonate based anhydrous deodorant composition|
    PCT/FR2016/051095| WO2016185113A1|2015-05-21|2016-05-10|Anhydrous deodorant composition made from bicarbonate|
    [返回顶部]